There is a ferry that travels between Mayagüez in Puerto Rico and Santo Domingo in Dominican Republic. The website says the journey takes 12 hours, leaves Puerto Rico on Mondays, Wednesdays and Fridays at 8PM, and arrives in Dominican Republic at 8AM the next morning.
For prices and bookings, visit the Ferries Del Caribe English website .
NOTE: According to an artice on DiarioLibre.com, the ferry service between Puerto Rico and the Dominican Republic "temporarily" ceased on 15 April 2010 due to a conflict between the company Ferries del Caribe and the administration of the Port of Mayaguez.
NOTE: As of March 1, 2011 ferry service has returned, it now sails from Mayagüez and San Juan. Check their website for schedules.
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